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Siva is the greatest of all demigods
SB Canto 1
The Lord is worshipable even by Brahmā and Śiva, the greatest of all demigods.
SB 1.16.26-30, Purport: This material world is a product of the mahat-tattva, which is a state of the Lord's dreaming condition in His yoga-nidrā mystic slumber in the Causal Ocean, and yet the whole creation appears to be a factual presentation of His creation. This means that the Lord's dreaming conditions are also factual manifestations. He can therefore bring everything under His transcendental control, and thus whenever and wherever He does appear, He does so in His fullness. The Lord, being all that is described above, maintains the affairs of the creation, and by His so doing He gives salvation even to His enemies who are killed by Him. He is attractive even to the topmost liberated soul, and thus He is worshipable even by Brahmā and Śiva, the greatest of all demigods. Even in His incarnation of puruṣa-avatāra He is the Lord of the creative energy. The creative material energy is working under His direction, as confirmed in the Bhagavad-gītā (9.10). He is the control switch of the material energy, and to control the material energy in the innumerable universes, He is the root cause of innumerable incarnations in all the universes.
SB Canto 3
Lord Śiva's uncivilized, devilish characteristics are never abominable because he teaches the sincere devotees of the Lord how to practice detachment from material enjoyment. He is called Mahādeva, or the greatest of all demigods, and no one is equal to or greater than him in the material world.
SB 3.14.27, Purport: Lord Śiva's uncivilized, devilish characteristics are never abominable because he teaches the sincere devotees of the Lord how to practice detachment from material enjoyment. He is called Mahādeva, or the greatest of all demigods, and no one is equal to or greater than him in the material world. He is almost equal with Lord Viṣṇu. Although he always associates with Māyā, Durgā, he is above the reactionary stage of the three modes of material nature, and although he is in charge of devilish characters in the mode of ignorance, he is not affected by such association.
SB Canto 4
SB 4.2.2, Translation: Lord Śiva, the spiritual master of the entire world, is free from enmity, is a peaceful personality, and is always satisfied in himself. He is the greatest among the demigods. How is it possible that Dakṣa could be inimical towards such an auspicious personality?
There was a tumultuous roaring all over the universe in the societies of the demigods of different planets because Satī was the daughter of Dakṣa, the greatest of all kings, and the wife of Lord Śiva, the greatest of all demigods.
SB 4.4.28, Purport: There was a tumultuous roaring all over the universe in the societies of the demigods of different planets because Satī was the daughter of Dakṣa, the greatest of all kings, and the wife of Lord Śiva, the greatest of all demigods. Why did she become so angry that she gave up her body? Since she was the daughter of a great personality and wife of a great personality, she had nothing to desire, but still she gave up her body in dissatisfaction. Certainly this was astonishing. One cannot attain complete satisfaction even if one is situated in the greatest material opulence. There was nothing Satī could not achieve either from her relationship with her father or from her relationship with the greatest of the demigods, but still, for some reason, she was dissatisfied. Therefore, Śrīmad-Bhāgavatam (1.2.6) explains that one has to achieve real satisfaction (yayātmā suprasīdati), but ātmā—the body, mind and soul—all become completely satisfied only if one develops devotional service to the Absolute Truth. Sa vai puṁsāṁ paro dharmo yato bhaktir adhokṣaje. Adhokṣaja means the Absolute Truth. If one can develop his unflinching love for the transcendental Supreme Personality of Godhead, that can give complete satisfaction, otherwise there is no possibility of satisfaction in the material world or anywhere else.
SB Canto 8
SB 8.7.21, Translation: The prajāpatis said: O greatest of all demigods, Mahādeva, Supersoul of all living entities and cause of their happiness and prosperity, we have come to the shelter of your lotus feet. Now please save us from this fiery poison, which is spreading all over the three worlds.
Other Books by Srila Prabhupada
Krsna, The Supreme Personality of Godhead
Rukmiṇī said that she did not think anyone was greater than Kṛṣṇa, not even Lord Śiva, who is known as Mahādeva, the greatest of all demigods.
Krsna Book 52: To avoid the unnecessary killing of her relatives, Rukmiṇī suggested that it would be easiest for Him to kidnap her while she was either going from the palace to the temple or else returning home. She also explained to Kṛṣṇa why she was anxious to marry Him, even though her marriage was to take place with Śiśupāla, who was also qualified, being the son of a great king. Rukmiṇī said that she did not think anyone was greater than Kṛṣṇa, not even Lord Śiva, who is known as Mahādeva, the greatest of all demigods. Lord Śiva also seeks the pleasure of Lord Kṛṣṇa in order to be delivered from his entanglement in the quality of ignorance within the material world. Although Lord Śiva is the greatest of all great souls, mahātmās, he keeps on his head the purifying water of the Ganges, which emanates from a hole in this material universe made by the toe of Lord Viṣṇu. Lord Śiva is in charge of the material quality of ignorance, and to keep himself in a transcendental position he always meditates on Lord Viṣṇu, or Kṛṣṇa, and always tries to purify himself with the water of the Ganges.